A novel selenophene based non-fullerene acceptor for near-infrared organic photodetectors with ultra-low dark current
Zhuoran Qiao, Qiao He, Alberto D Scaccabarozzi, Julianna Panidi, Adam Marsh, Yang Han, Polina Jacoutot, Davide Nodari, Tianyi Zhang, Amirah Way, Andrew JP White, Thomas D Anthopoulos, Wing Chung Tsoi, Artem A Bakulin, Martin Heeney, Zhuping Fei, Nicola Gasparini
Journal of Materials Chemistry C
2024
Near-infrared organic photodetectors (OPDs) have great potential in many applications. However, the high dark current of many OPD devices tends to limit their specific detectivity and overall performance. Here we report a novel non-fullerene acceptor (IDSe) based on an alkylated indacenodiselenophene core, with extended light absorption up to 800 nm. When blended with the donor polymer PTQ10, we obtained OPD devices with an exceptionally low dark current density of 1.65 nA cm−2 at −2 V, high responsivity and specific detectivity exceeding 1012 Jones at 790 nm. The superior properties of PTQ10:IDSe devices are related to the higher and more balanced charge carrier mobility compared to the analogous thiophene based blend (PTQ10:IDIC). We also demonstrate large area PTQ10:IDSe based devices by doctor blade in air with a record low dark current of 1.2 × 10−7 A cm−2 under −2 V bias.